中国陆相油页岩含油率与总有机碳的响应机理     

贾建亮  刘招君  孟庆涛  孙平昌  徐进军  柳蓉  白悦悦 《吉林大学学报(地球科学版)》2020,50(2):368-377

为了建立稳定可靠的利用油页岩总有机碳预测含油率的模型，揭示中国陆相不同成因类型油页岩含油率与总有机碳的内在关系极其重要。通过不同类型盆地油页岩钻井取心测试的关键参数，结合沉积学、有机地球化学、热模拟等学科技术，探讨油页岩含油率与总有机碳的响应机理。结果表明：不同盆地类型与沉积背景下发育的油页岩含油率与总有机碳质量分数均呈现良好的正相关性（R²=0.81~0.97）；中国陆相油页岩的成因类型进一步划分为5种类型，制约着含油率与总有机碳的内在关系；油页岩的升温加热模拟呈现3个失重阶段（温度<150、300~550、600~750℃），明确了含油率与总有机碳参数的物理意义；相同类型盆地与沉积背景下形成的油页岩具有相近的母质生源组合，从而具有大致相当的再生烃效率。中国陆相油页岩成因类型的细划、含油率与总有机碳物理意义的明确、油页岩再生烃能力的分析，有助于理解中国陆相油页岩含油率与总有机碳的内在响应关系。  相似文献   

Effect of Shale Reservoir Characteristics on Shale Oil Movability in the Lower Third Member of the Shahejie Formation,Zhanhua Sag     

NING Chuanxiang  MA Zhongliang  JIANG Zhenxue  SU Siyuan  LI Tingwei  ZHENG Lunju  WANG Guozhen  LI Fengxun 《《地质学报》英文版》2020,94(2):352-363

To reveal the effect of shale reservoir characteristics on the movability of shale oil and its action mechanism in the lower third member of the Shahejie Formation(Es3l), samples with different features were selected and analyzed using N2 adsorption, high-pressure mercury injection capillary pressure(MICP), nuclear magnetic resonance(NMR), high-speed centrifugation, and displacement image techniques. The results show that shale pore structure characteristics control shale oil movability directly. Movable oil saturation has a positive relationship with pore volume for radius > 2 μm, as larger pores often have higher movable oil saturation, indicating that movable oil is present in relatively larger pores. The main reasons for this are as follows. The relatively smaller pores often have oil-wetting properties because of organic matter, which has an unfavorable effect on the flow of oil, while the relatively larger pores are often wetted by water, which is helpful to shale oil movability. The rich surface provided by the relatively smaller pores is beneficial to the adsorption of immovable oil. Meanwhile, the relatively larger pores create significant pore volume for movable oil. Moreover, the larger pores often have good pore connectivity. Pores and fractures are interconnected to form a complex fracture network, which provides a good permeability channel for shale oil flow. The smaller pores are mostly distributed separately;thus, they are not conducive to the flow of shale oil. The mineral composition and fabric macroscopically affect the movability of shale oil. Calcite plays an active role in shale oil movability by increasing the brittleness of shale and is more likely to form micro-cracks under the same stress background. Clay does not utilize shale oil flow because of its large specific surface area and its block effect. The bedding structure increases the large-scale storage space and improves the connectivity of pores at different scales, which is conducive to the movability of shale oil.  相似文献   

Establishment and application of an intelligent treating method for oil spill identification     

TAN Liju  ZHAO Ruxiang  YIN Xiaonan  ZHANG Haijiang  WANG Jiangtao 《海洋学报(英文版)》2018,37(11):116-122

In the identifying process of an oil spill accident, manual integral and artificial visual comparison are commonly used at present to determine the oil spill sources, these methods are time-consuming and easily affected by human factors. Therefore, it is difficult to achieve the purpose of rapid identification of an oil spill accident. In this paper, an intelligent method of automatic recognition, integration and calculation of diagnostic ratio of Gas Chromatography-Mass Spectrometer (GC/MS) spectrum are established. Firstly, four hundreds of samples collected around the world were analyzed using a standard method and Retention time locking technology (RTL) was applied to reduce the change of retention time of GC/MS spectrum. Secondly, the automatic identification, integration of n-alkanes, biomarker compounds, polycyclic aromatic hydrocarbons and calculation of the diagnostic ratios were realized by MATLAB software. Finally, a database of oil fingerprints were established and applied successfully in a spill oil accident. Based on the new method and database, we could acquire the diagnostic ratios of an oil sample and find out the suspected oil within a few minutes. This method and database can improve the efficiency in spilled oil identification.  相似文献   

多极化SAR溢油探测影响因素分析研究     

宋莎莎  赵朝方  安伟  李晓峰  王臣 《海洋学报(英文版)》2018,37(11):77-87

Polarimetric synthetic aperture radar(SAR) oil spill detection parameters conformity coefficient(μ), Muller matrix parameters(|C|, B_0), the eigenvalues of simplified coherency matrix(λ_(nos)) and the influence of SAR observing parameters, ocean environment and noise level are investigated. Radarsat-2 data are used to make systematic analysis of polarimetric parameters for different incidences, wind speeds, noise levels and the ocean phenomena(oil slick and look likes). The influence of the SAR observing parameters, the ocean environment and the noise level on the typical polarimetric SAR parameter conformity coefficient has been analyzed. The results indicate that conformity coefficient cannot be simply used for oil spill detection, which represents the image signal to the noise level to some extent. When the signals are below the noise level for the oil slick and the look likes, the conformity coefficients are negative; while the signals above the noise level corresponds to positive conformity coefficients. For dark patches(low wind and biogenic slick) with the signal below the noise,polarization features such as conformity coefficient cannot separate them with oil slick. For the signal above the noise, the oil slick, the look likes(low wind and biogenic slick) and clean sea all have positive conformity coefficients, among which, the oil slick has the smallest conformity coefficient, the look likes the second, and the clean sea the largest value. For polarimetric SAR data oil spill detection, the noise plays a significant role. So the polarimetric SAR data oil spill detection should be carried out on the basis of noise consideration.  相似文献   

美国海上油气田租赁开发和环评体系研究          下载免费PDF全文

金嘉萌  黄必桂  安明明 《海洋开发与管理》2018,35(7):30-35

美国海洋油气环评贯穿于外大陆架油气区域租赁销售和开发的各个阶段。文章从美国外大陆架租赁范围界定入手,介绍油气区域租赁开发所经历的5年规划、区域销售、勘探和开发生产各阶段所涉及的环评文件类型。着重分析美国海洋油气开发环评体系、工作程序和文件内容,最后提出对我国海洋油气开发环评的启示,即:海洋油气规划环评在先;公众参与的早期介入;全过程政府环评;环评审查不等于排污许可。  相似文献   

溢油乳化过程C波段微波散射特性实验研究     

舒思京  孟俊敏  张晰  过杰  刘根旺 《海洋学报(英文版)》2020,39(7):135-145

本文基于水槽溢油观测实验，研究溢油乳化过程中表面散射特性的变化。利用全极化C波段微波散射计和矢量网络分析仪等测量设备对易发生乳化反应沥青含量小于3%的原油（A型油）、油田中开采出的新鲜原油（B型油）和经过脱水去杂质处理的工业原油（C型油）进行观测。文中详细分析了在C波段微波下乳化油膜与平静水面的后向散射差异，以及油膜乳化过程对后向散射的影响，结果显示在低风速、无浪的条件下（最大波高低于3mm），原油的乳化反应可通过表面粗糙度和自身介电常数的变化来调制雷达后向散射，并且这两种方式中表面粗糙度的影响占主导地位。对比B型和C型原油在乳化状态和未乳化状态下的表面后向散射，结果显示在各状态下B型油膜表面后向散射均大于C型油，且在VV、HH、HV/VH极化方式下两者后向散射平均差异分别为2.19 dB、2.63 dB、2.21 dB，在20%油膜含水率的乳化状态下差异较未乳化状态时小，平均差异分别为0.98 dB、1.49 dB、1.5 dB，结果表明不同类型油种间由于成分和油膜属性的不同会在一定程度上导致油膜表面粗糙度存在差异，影响油膜表面后向散射。  相似文献   

溢油对海洋生态系统内在价值损害的评估——以“塔斯曼海”轮溢油事故为例     

严志宇  孙冰  付红蕊  任杰 《海洋科学》2020,44(4):85-89

作者籍以能值和生态炯分析,将海洋生态内在价值补充到溢油损害评估中,并以"塔斯曼海"轮溢油事故为例,分析了生态系统内在价值损害评估的特点。结果表明溢油生态内在价值损害大于对生态服务价值的损害,前者是后者的6.9倍;能值变化反映对资本积累的损害,生态炯更突出了溢油对初级生产力的生态系统的影响。本评价是现有溢油损害评价的补充,可为彻底、有效环境治理、生态修复提供保障,对海洋开发管理决策和公众环保意识的提高将有积极的影响。  相似文献   

基于热红外图像的海面油膜面积的测算方法     

王利锋  辛丽平  于波  鞠莲  魏来  胡湛波 《海洋通报》2020,39(6):750-760

针对现有油膜检测技术难以准确测算油膜面积且检测精度受天气条件影响大的问题，本文提出了一种基于热红外图像的海面油膜面积测算方法。采用波段为 8耀14 滋m 的红外热像仪获取海面油膜的热红外图像，对采集的油膜图像进行预处 理 （灰度化、中值滤波和锐化）；基于图像灰度分布特征分割油膜区域 （感兴趣区域，ROI），采用形态学操作对 ROI 进行填充、腐蚀与膨胀，并对 ROI 进行数学表征；通过像素面积法计算 ROI 实际物理面积。实验结果表明：在不同的外界天气环境下 （如海浪、海风、海雾、不同光照等环境），该方法对不同黏度的石油样品在海面形成的油膜均有良好的检测精度， ROI 面积计算平均误差为 3.77%。  相似文献   

南海北部海域油气勘探保障建设选址适宜性研究     

武二亮  陈浩东  刘裕光  安永宁 《海岸工程》2020,39(4):256-262

为分析南海北部海域油气勘探保障建设选址的适宜性,在广泛研究备选区特征资料的基础上,基于层次分析法(Analytic Hierarchy Process, AHP)原理,以自然环境因素、开发环境因素、基础设施与投资情况以及其他因素作为一级评判准则,建立了包括12项二级评判准则的递进层次结构模型,并以永兴岛、赵述岛和晋卿岛作为3个假定备选区,来验证分析评价模型的有效性和可靠性。AHP评判结果显示,3个备选区的整体优劣指数依次为0.587 1, 0.212 1, 0.200 8;AHP模型的一致性比例CR值为0.020 3。通过分析和筛选影响远海油气勘探保障建设的选址因子,构建基于AHP原理的选址评价模型,可用于分析评价南海北部岛礁油气勘探保障建设选址的适宜性。  相似文献   

3500m岩心钻探装备在油气井勘查中的示范应用     

任启伟  刘凡柏  高鹏举  赵远  伍晓龙 《探矿工程》2018,45(10):57-61

3500 m岩心钻探装备（YDX—6型钻机）是我国自主研发的深部矿产资源勘查技术装备,采用N级口径钻深可达3500 m,其最大特点是采用长油缸钻进和起下钻。本文主要介绍了该钻机在油气井勘查中生产试验情况,同时对矿区地层、钻孔结构、钻进过程、钻进效果、遇到的主要问题及解决办法等进行了介绍。  相似文献